|
13.
Effect of Metal Oxides on the Structure - Property Relationship of
Poly(diphenylamine)
R.
Anbarasana*, S.A. Anton Kumananb, R. Sivab, V.
Dhanalakshmib
aDepartment
of Chemical Engineering, Nano Biotechnology Research Laboratory,
National Taiwan University, Taipei – 10617, Taiwan, PR of China,
bDepartment of Polymer Technology, Kamaraj College of Engineering
and Technology, Virudhunagar – 626 001, Tamil Nadu, India.
Corresponding author: R.Anbarasan (anbu_may3@yahoo.co.in
)
Abstract:
Diphenylamine (DPA) was polymerized with two different initiator
namely potassium peroxy disulphate (PDS) and potassium
dichromate (PDC) under inert atmosphere at 45oC in the presence
and absence of various nano materials. Rp was determined based
on gravimetric method. FTIR will account for the % amino and %
imino forms of backbone of Poly(diphenylamine) (PDPA). Added
nano materials improved the thermal degradation temperature of
PDPA as well as their electrical conductivity value.
Keywords:
Poly(diphenylamine), nanocomposites, Rp, FTIR, TGA, Conductivity,
HRTEM
<<< |
