13.
Comparative Studies of the Inhibitory Properties of Schiff Bases (LPYA
and LPHA) on Mild Steel Corrosion in 0.5M HCl
Kalada Hart*, N.C Oforka and A.O James
Department of Pure and Industrial
Chemistry, P.M.B.5323, University of Port-Harcourt, Port-Harcourt,
Nigeria. *Corresponding author. Email:
1kaladahart@yahoo.com & 3bidean2002@yahoo.com
Abstract:
The weight loss method has been used to study the corrosion
inhibitory properties of Schiff bases (LPYA and LPHA) on Mild
Steel Corrosion in 0.5M HCl. Maximum inhibition efficiency was
obtained at an optimum concentration of 1.0×10-2M and highest
temperature of 353K for both Schiff bases. A higher inhibition
efficiency of 99.30% was obtained for LPYA while 77.01% for LPHA
at the same temperature and concentration. However an increase
in temperature increased the inhibition efficiencies of both
Schiff bases. The phenomenon of chemical adsorption has been
proposed for both Schiff bases since an increase in temperature
showed a corresponding increase in their inhibition efficiency.
Keywords: Corrosion; Inhibition; Mild steel; Temperature; N–{[-2
Pyridine–2–azo)–5–Hydroxyl] Phenyl}–4–Methoxybenzilidenimine (LPYA);
N–{[2–(3–hydroxyphenylazo)–5–hydroxyl] phenyl}–4–methoxy
benzilidene (LPHA).
<<< |