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14.
Trans-[PtCl2(NH2C6H4CO2H)2]:
A Platinum Complex Forming A Two-Dimensional Hydrogen-Bonded Network
Ayi
A. Ayi*,1,2 Andrew D. Burrows,1 Mary F. Mahon1
and Anna J. Warren1
1 (Department of
Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK).
2 (Department of Pure
and Applied Chemistry, University of Calabar, P.M.B. 1115, Calabar,
Nigeria).
*corresponding author:
ayiayi72@gmail.com
or
ay_72000@yahoo.com
Abstract.
The compound trans-[PtCl2(NH2C6H4CO2H)2]
has been shown to form a two-dimensional hydrogen-bonded network
in the solid state, with pairs of O–H···O hydrogen bonds between
carboxylic acid groups linking the molecules into zigzag tapes,
which are cross-linked into sheets by pairs of N–H···Cl hydrogen
bonds.
Keywords: Metal-organic frameworks, Metalloligands,
two-dimensional hydrogen-bonded network
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